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KMID : 1024520180270020109
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Journal of the Environmental Sciences
2018 Volume.27 No. 2 p.109 ~ p.122
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Treatment Characteristics of Acid Mine Drainage by Porous Ceramics using Wood Flour as Pore-forming Agent
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Yim Soo-Bin
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Abstract
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This study was conducted to investigate the removal characteristics of heavy metals and sulfate ion from acid mine drainage by porous zeolite-slag ceramics (ZS ceramics) that was prepared by adding wood flour as pore-foaming agent while calcining the mixtures of natural zeolite and converter slag. The batch test showed that the removal efficiency of heavy metals by pellet-type porous ZS ceramics increased as the particle size of wood flour was decreased and as the weight mixing ratio of wood flour to ZS ceramics was increased. The optimal particle size and weight mixing ratio of wood flour were measured to be 75um and 7~10%, respectively. The removal test with the porous ZS ceramics prepared in these optimal condition showed very high removal efficiencies: more than 98.4% for all heavy metals and 73.9% for sulfate ion. Relative to nonporous ZS ceramics, the increment of removal efficiency of heavy metals by porous ZS ceramics with 75um and 10% wood flour was 5.8%, 60.5%, 36.9%, 87.7%, 10.3%, and 57.4% for Al, Cd, Cu, Mn, Pb, and Zn, respectively. The mechanism analysis of removal by the porous ZS ceramics suggested that the heavy metals and sulfate ion from acid mine drainage are eliminated by multiple reactions such as adsorption and/or ion exchange as well as precipitation and/or co-precipitation.
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KEYWORD
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Acid mine drainage, Porous Zeolite-Slag (ZS) ceramics, Wood flour, Pore-forming agent, Precipitation, Adsorption
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